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Neither, most chemicals are actual medical drugs manufactured by pharmaceutical companies who don't consent to their medicine being used to kill people. So prisons aren't allowed to use them as such or face charges, and that's that.
So they have to use some homebrew cocktails or overdose prisoners on stuff that isn't highly lethal, so it takes forever.
As far as I remember, the drugs can't be legally produced or sold in the US, so they have to be smuggled in from India. But I may be off on the details. Either case, what the fuck.