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Actually with nitrogen it's not tricky at all.
Gas chambers use toxic cyanide gas which is extremely painful to breathe in. After the execution the corpse has to be decontaminated so it does not poison mortuary workers. This is not a good system.
The air you are breathing right now is about 80% nitrogen (and 20% oxygen). Nitrogen is all around us. You breathe it with every breath. It is harmless and non-toxic.
Execution by nitrogen does not kill the prisoner because they are breathing nitrogen. It kills the prisoner because breathing 100% nitrogen means they are not breathing any oxygen. Our bodies need a constant flow of oxygen to survive. Remove that, even by simply displacing all the oxygen with a harmless substitute, and the person dies.
Thus if done correctly, all you really need is a breathing mask. You can have other people right next to the prisoner during the execution and they will suffer no ill effect as long as the room is generally ventilated.