Reishi mushroom powder is surprisingly chocolatey.
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There is no substitute for pure cocoa, unfortunately. The best you can do is buy from Fair Trade sellers, but they only certify the cooperative groups they trade with, and not the actual farms afaik.
Peanut butter powder?
Instant coffee
Malt extract
Peanut four
Cinnamon
There is no substitute for chocolate. I'd make a protein shake and blend in some fruit. Bananas and frozen berries are great.
Carob?
Nobody likes carob. Anyone who says it's good is lying or deluded. It's most definitely not a replacement for chocolate.
I wouldn't say it is a perfect replacement, but I have eaten a few carob flavored cookies for dogs and it was close enough to chocolate for me to suggest it.