Intel
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CPU Cooling problems: Just like 95C is normal for Ryzen, 100C is normal for Intel CPUs in many workloads. If you're worried about CPU temperatures, please look at reviews for the laptop or CPU cooler you're using.
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I had a worse AIO than you and my 12900K at 300W managed to just hit 100°C.
Your cooler is not doing its job.
First of all, use good thermal paste like Kryonaut or Thermalright TFX, and use a Thermalright LGA 1700 contact frame.
Second of all, ensure your AIO works and double check all connections.
Third of all, use HWiNFO64.