They will, they've just not updated the QVL list.
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48gb x 4 slots (192gb) max right?
The MSI QVL you provided in the link already has support for 64GB kits. I think the way they presented the information can be misleading. The "Size" refers to the size of a single module (stick) and "1|2|4 DIMM" refers to how many sticks they have verified the XMP to work.
So if you're interested in 64GB 2 stick kits, you have to look at "Size" of 32GB and "1|2|4 DIMM" of √ | √ | .